Air filter medium, air filter pack, and air filter unit

ABSTRACT

An air filter medium includes a first porous PTFE membrane and a second porous PTFE membrane. The air filter medium has a first main surface and a second main surface, and the first porous PTFE membrane and the second porous PTFE membrane are arranged so that an air flow moving from the first main surface to the second main surface passes through the first porous PTFE membrane and subsequently through the second porous PTFE membrane. A contact angle of the first porous PTFE membrane with water is in the range of 154° to 165°.

TECHNICAL FIELD

The present invention relates to an air filter medium including a porousmembrane of polytetrafluoroethylene (hereinafter referred to as “PTFE”).

BACKGROUND ART

Porous PTFE membranes have been conventionally used as air filter mediain a variety of fields. Porous PTFE membranes, which have high dustcollection performance, are very suitable for use in a place with alittle amount of dust (such as use in a clean room). However, when aporous PTFE membrane is used in an intake air filter for an outdoor airconditioner or turbine to filter out air dust, the porous PTFE membranemay collect air-borne dust only in its surface portion and beconsequently clogged, causing an increase in pressure drop. An attempthas thus been made to prevent clogging of a porous PTFE membrane andincrease the service life of an air filter medium by disposing anair-permeable member such as a non-woven fabric as a prefilter layer onthe upstream side in the air flow direction to collect large particlesof dust in advance (Patent Literature 1). However, the air filter mediumdescribed in Patent Literature 1 has a problem in that the achievementof the preventive effect on clogging of the porous PTFE membranerequires thickening of the prefilter layer, which leads to a highmanufacturing cost. There is also a problem in that thickening of theprefilter layer makes pleating (folding into a series of W-shapes) ofthe air filter medium difficult.

As a product designed to prevent clogging of porous PTFE membranes withdust, there has been proposed an air filter medium in which a firstporous PTFE membrane and a second porous PTFE membrane are stacked, theaverage pore diameter of the second porous PTFE membrane is larger thanthe average pore diameter of the first porous PTFE membrane, and thesecond porous PTFE membrane is disposed upstream of the first porousPTFE membrane in an air flow direction (Patent Literature 2). PatentLiterature 2 states that the second porous PTFE membrane functions as aprefilter to collect large-diameter particles of dust, thus reducing theincrease in the pressure drop across the air filter medium ([0006]). Inthe air filter medium of Patent Literature 2, the average pore diametersof the porous PTFE membranes are controlled to reduce the increase inpressure drop, as is evident from the fact that the collectionefficiency of the air filter medium is measured using polydispersedioctyl phthalate (DOP) with a particle diameter of 0.1 to 0.2 μm.

CITATION LIST Patent Literature

Patent Literature 1: JP 2000-300921 A

Patent Literature 2: JP 2001-170424 A

SUMMARY OF INVENTION Technical Problem

A recent problem concerning air filter media, in particular air filtermedia for clean rooms intended for medical treatment or pharmaceuticaloperation, is that not only dust floating in air but also oil mist (oilparticles) causes clogging leading to an increase in pressure drop.However, the air filter medium disclosed in Patent Literature 2 is notadapted to resist clogging with oil mist.

It is an object of the present invention to provide an air filter mediumresistant not only to clogging with dust floating in air but also toclogging with oil mist.

Solution to Problem

That is, the present invention provides an air filter medium including afirst porous PTFE membrane and a second porous PTFE membrane, wherein

the air filter medium has a first main surface and a second mainsurface,

the first porous PTFE membrane and the second porous PTFE membrane arearranged so that an air flow moving from the first main surface to thesecond main surface passes through the first porous PTFE membrane andsubsequently through the second porous PTFE membrane, and

a contact angle of the first porous PTFE membrane with water is in therange of 154° to 165°.

Advantageous Effects of Invention

The present invention can provide an air filter medium resistant notonly to clogging with dust floating in air but also to clogging with oilmist.

BRIEF DESCRIPTION OF DRAWINGS

FIG. 1 is a schematic cross-sectional view showing an air filter mediumas an embodiment of the present invention.

FIG. 2 is a schematic cross-sectional view showing an air filter mediumas another embodiment of the present invention.

FIG. 3 is a schematic cross-sectional view showing an air filter mediumas still another embodiment of the present invention.

FIG. 4 is a schematic cross-sectional view showing an air filter mediumas still another embodiment of the present invention.

FIG. 5 is a schematic cross-sectional view showing an air filter mediumas still another embodiment of the present invention.

FIG. 6 is a schematic cross-sectional view showing an air filter mediumas still another embodiment of the present invention.

FIG. 7A is a perspective view showing an air filter unit as anembodiment of the present invention.

FIG. 7B is a cross-sectional view of the air filter unit shown in FIG.7A.

FIG. 8A is a plan view of a T-type embossed non-woven fabric.

FIG. 8B is a plan view of an S-type embossed non-woven fabric.

FIG. 9 is a diagram illustrating contact angle measurement.

DESCRIPTION OF EMBODIMENTS

Hereinafter, embodiments of the present invention will be described withreference to FIGS. 1 to 6. The main surface of the air filter mediumthat is located on the upper side of each figure is defined as a firstmain surface 11, and the main surface opposite to the first main surface11 is defined as a second main surface 12. In all of the figures, it isassumed that the upper side of the figure corresponds to the upstreamside in the air flow direction when the air filter medium is placed inuse. The “main surfaces” refer to the widest surfaces, namely the upperand lower surfaces, of the air filter medium.

An air filter medium 10 shown in FIG. 1 includes a first porous PTFEmembrane 1 and a second porous PTFE membrane 2. As shown in FIG. 1, theair filter medium 10 has a multilayer structure composed of the firstporous PTFE membrane 1 and second porous PTFE membrane 2 which arearranged in this order from the upstream side in the air flow direction.A surface of the first porous PTFE membrane 1 forms the first mainsurface 11 of the air filter medium 10. A surface of the second porousPTFE membrane 2 forms the second main surface 12 of the air filtermedium 10. The first porous PTFE membrane 1 is stacked directly on thesecond porous PTFE membrane 2.

Air filter media 20, 30, and 40 shown in FIGS. 2 to 4 include anair-permeable fiber layer 3 in addition to the first porous PTFEmembrane 1 and the second porous PTFE membrane 2.

The air filter medium 20 shown in FIG. 2 has a multilayer structurecomposed of the first porous PTFE membrane 1, air-permeable fiber layer3, and second porous PTFE membrane 2 which are arranged in this orderfrom the upstream side in the air flow direction. A surface of the firstporous PTFE membrane 1 forms the first main surface 11 of the air filtermedium 20. A surface of the second porous PTFE membrane 2 forms thesecond main surface 12 of the air filter medium 20. The first porousPTFE membrane 1 is in contact with one surface of the air-permeablefiber layer 3, while the second porous PTFE membrane 2 is in contactwith the other surface of the air-permeable fiber layer 3.

The air filter medium 30 shown in FIG. 3 has a multilayer structurecomposed of the first porous PTFE membrane 1, second porous PTFEmembrane 2, and air-permeable fiber layer 3 which are arranged in thisorder from the upstream side in the air flow direction. A surface of thefirst porous PTFE membrane 1 forms the first main surface 11 of the airfilter medium 30. A surface of the air-permeable fiber layer 3 forms thesecond main surface 12 of the air filter medium 30. The first porousPTFE membrane 1 is in contact with one surface of the second porous PTFEmembrane 2, while the air-permeable fiber layer 3 is in contact with theother surface of the second porous PTFE membrane 2.

The air filter medium 40 shown in FIG. 4 has a multilayer structurecomposed of the air-permeable fiber layer 3, first porous PTFE membrane1, and second porous PTFE membrane 2 which are arranged in this orderfrom the upstream side in the air flow direction. A surface of theair-permeable fiber layer 3 forms the first main surface 11 of the airfilter medium 40. A surface of the second porous PTFE membrane 2 formsthe second main surface 12 of the air filter medium 40. Theair-permeable fiber layer 3 is in contact with one surface of the firstporous PTFE membrane 1, while the second porous PTFE membrane 2 is incontact with the other surface of the first porous PTFE membrane 1. Whenviewed from the first porous PTFE membrane 1, the air-permeable fiberlayer 3 is disposed on a side opposite to a side where the second porousPTFE membrane 2 is disposed.

An air filter medium 50 shown in FIG. 5 includes two air-permeable fiberlayers 3 in addition to the first porous PTFE membrane 1 and the secondporous PTFE membrane 2. The two air-permeable fiber layers 3 include afirst air-permeable fiber layer 3 a and a second air-permeable fiberlayer 3 b. The air filter medium 50 has a multilayer structure composedof the first air-permeable fiber layer 3 a, first porous PTFE membrane1, second porous PTFE membrane 2, and second air-permeable fiber layer 3b which are arranged in this order from the upstream side in the airflow direction. The first air-permeable fiber layer 3 a forms the firstmain surface 11 of the air filter medium 50. The second air-permeablefiber layer 3 b forms the second main surface 12 of the air filtermedium 50. The first air-permeable fiber layer 3 a is in contact withone surface of the first porous PTFE membrane 1, while the second porousPTFE membrane 2 is in contact with the other surface of the first porousPTFE membrane 1. The second air-permeable fiber layer 3 b is in contactwith one surface of the second porous PTFE membrane 2, while the firstporous PTFE membrane 1 is in contact with the other surface of thesecond porous PTFE membrane 2. When viewed from the first porous PTFEmembrane 1, the first air-permeable fiber layer 3 a is disposed on aside opposite to a side where the second porous PTFE membrane 2 isdisposed. When viewed from the second porous PTFE membrane 2, the secondair-permeable fiber layer 3 b is disposed on a side opposite to a sidewhere the first porous PTFE membrane 1 is disposed.

An air filter medium 60 shown in FIG. 6 includes three air-permeablefiber layers 3 in addition to the first porous PTFE membrane 1 and thesecond porous PTFE membrane 2. The three air-permeable fiber layers 3include a first air-permeable fiber layer 3 a, a second air-permeablefiber layer 3 b, and a third air-permeable fiber layer 3 c. The airfilter medium 60 has a multilayer structure composed of the firstair-permeable fiber layer 3 a, first porous PTFE membrane 1, thirdair-permeable fiber layer 3 c, second porous PTFE membrane 2, and secondair-permeable fiber layer 3 b which are arranged in this order from theupstream side in the air flow direction. The first air-permeable fiberlayer 3 a forms the first main surface 11 of the air filter medium 60.The second air-permeable fiber layer 3 b forms the second main surface12 of the air filter medium 60. The first air-permeable fiber layer 3 ais in contact with one surface of the first porous PTFE membrane 1,while the third air-permeable fiber layer 3 c is in contact with theother surface of the first porous PTFE membrane 1. The secondair-permeable fiber layer 3 b is in contact with one surface of thesecond porous PTFE membrane 2, while the third air-permeable fiber layer3 c is in contact with the other surface of the second porous PTFEmembrane 2. When viewed from the first porous PTFE membrane 1, the firstair-permeable fiber layer 3 a is disposed on a side opposite to a sidewhere the second porous PTFE membrane 2 is disposed. When viewed fromthe second porous PTFE membrane 2, the second air-permeable fiber layer3 b is disposed on a side opposite to a side where the first porous PTFEmembrane 1 is disposed.

In the air filter media 10, 20, 30, 40, 50, and 60 shown in FIGS. 1 to6, as seen from the foregoing, the first porous PTFE membrane 1 and thesecond porous PTFE membrane 2 are arranged so that an air flow movingfrom the first main surface 11 to the second main surface 12 passesthrough the first porous PTFE membrane 1 and subsequently through thesecond porous PTFE membrane 2. The air filter medium according to thepresent invention is not limited to the configurations shown in FIGS. 1to 6 and may further include an additional layer. Examples of theadditional layer include a glass filter medium, a melt-blown non-wovenfabric, and a nanofiber layer which may be disposed upstream of thefirst porous PTFE membrane 1.

Hereinafter, the layers constituting the air filter media 10, 20, 30,40, 50, and 60 will be described.

<First Porous PTFE Membrane 1>

The first porous PTFE membrane 1 has moderate air permeability, andcollects relatively large-diameter particles of oil mist in advance toprevent the second porous PTFE membrane 2 from being clogged with oilmist. The presence of the first porous PTFE membrane 1 reduces apressure drop increase resulting from the use of the air filter media10, 20, 30, 40, 50, and 60, thus increasing the service life of the airfilter media 10, 20, 30, 40, 50, and 60.

It is inferred that due to capillary action, oil attached to the firstporous PTFE membrane 1 disposed on the upstream side in the air flowdirection permeates the first porous PTFE membrane 1 to reach to thesecond porous PTFE membrane 2. Clogging of the second porous PTFEmembrane 2 with oil is thought to be prevented by reduction ofpermeation of oil into the first porous PTFE membrane 1. Likelihood ofcapillary action largely depends on the contact angle of the firstporous PTFE membrane 1. A sufficiently large contact angle allows thefirst porous PTFE membrane 1 to collect and retain more oil.

In the present embodiment, the contact angle of the first porous PTFEmembrane 1 with water is in the range of 154° to 165°. When the contactangle of the first porous PTFE membrane 1 is within this range,permeation of oil into the first porous PTFE membrane 1 is reduced. Thefirst porous PTFE membrane 1 collects relatively large-diameterparticles of oil, and thus the second porous PTFE membrane 2 isprevented from being clogged with oil. Spreading of oil attached to thesurface of the first porous PTFE membrane 1 is also reduced. A dropletof oil tends to maintain a spherical shape on the first porous PTFEmembrane 1. That makes a droplet of oil less likely to block pores ofthe first porous PTFE membrane 1. Thus, the first porous PTFE membrane 1can collect and retain more oil while an increase in pressure drop isreduced. That is, the amount of retained oil can be increased whilepressure drop across the air filter medium is reduced.

The following equation (A) shows a relationship between the contactangle θ and the water entry pressure of a porous membrane. The waterentry pressure H on the left side represents the upper limit of thewater height at which water cannot pass through the porous membrane.According to the equation (A), the water entry pressure increases withan increasing contact angle θ (90°<θ≤180°). When the water entrypressure is high, oil is also less likely to permeate.H=−2T cos θ/Sgr  (A)

-   -   H: Water entry pressure [cm]    -   T: Surface tension of water [g/sec²]    -   S: Density of water [g/cm³]    -   g: Gravitational acceleration [cm/sec²]    -   θ: Contact angle with water    -   r: Radius of pores of porous membrane [cm]

The contact angle can be measured with a commercially-available contactangle meter. Specifically, a syringe with a needle is held so that thetip of the needle does not have contact with a specimen (porous PTFEmembrane). A 2 μL droplet (a droplet of distilled water) is forced outthrough the tip of the needle. With the droplet held at the tip of theneedle, the syringe is moved downward to let the droplet have contactwith the specimen. The syringe is moved upward to place the dropletalone on the specimen, and the contact angle of the droplet is measured.As shown in FIG. 9, the contact angle is an angle θ between a tangent ofa droplet 14 and a surface 16 of a specimen. The contact angle can bemeasured according to the sessile drop method specified in JapaneseIndustrial Standards (JIS) R 3257 (1999). The average of contact anglevalues measured at five points of a specimen can be adopted as thecontact angle of the specimen.

For the measurement of the contact angle, for example, a 2 μL droplet ofwater is used. It is difficult to measure the contact angle of theporous PTFE membrane with oil because a 2 μL droplet of oil dropped onthe porous PTFE membrane permeates the porous PTFE membrane. The contactangle of the porous PTFE membrane with water is indeed different fromthe contact angle of the porous PTFE membrane with oil. However, thecontact angle of the porous PTFE membrane with water and the contactangle of the porous PTFE membrane with oil show the same tendency.Therefore, it is sufficiently reasonable to adopt the contact angle ofthe porous PTFE membrane with water as a measure of the likelihood ofcapillary action of oil in the porous PTFE membrane. This is evidentalso from Examples described below.

As described with reference to FIGS. 4 to 6, the air-permeable fiberlayer 3 may be in contact with the surface of the first porous PTFEmembrane 1. In this case, the air-permeable fiber layer 3 can be peeledfrom the first porous PTFE membrane 1 to measure the contact angle ofthe first porous PTFE membrane 1. When the air-permeable fiber layer 3is, for example, a non-woven fabric which has a coarse texture, thesurface of the first porous PTFE membrane 1 can be exposed through theinterstices between the fibers of the non-woven fabric to measure thecontact angle of the first porous PTFE membrane 1. The other propertiesof the first porous PTFE membrane 1 can also be measured by peeling theair-permeable fiber layer 3 from the first porous PTFE membrane 1. Thesame applies to the second porous PTFE membrane 2.

Other structural features of the first porous PTFE membrane 1 will bedescribed.

It is preferable that the average pore diameter of the first porous PTFEmembrane 1 be larger than the average pore diameter of the second porousPTFE membrane 2, because in this case the effect on the resistance toclogging with oil mist is further enhanced. When the average porediameter of the first porous PTFE membrane 1 disposed on the upstreamside in the air flow direction is larger than the average pore diameterof the second porous PTFE membrane 2, the first porous PTFE membrane 1collects relatively large particles of oil mist in advance on theupstream side in the air flow direction while the second porous PTFEmembrane 2 collects smaller particles of oil mist on the downstream sidein the air flow direction. Thus, since both the first porous PTFEmembrane 1 and second porous PTFE membrane 2 can collect oil mist,clogging of the air filter medium can be further reduced.

The average pore diameter of the first porous PTFE membrane 1 is, forexample, 3 to 30 μm, preferably 4 to 21 μm, and more preferably 4 to 10μm. The average pore diameters of the first porous PTFE membrane 1 andthe second porous PTFE membrane 2 described later can be determined bymeasuring the pore diameter of each porous PTFE membrane at three ormore points with “Perm Porometer” manufactured by Porous Materials Inc.and calculating the average of the measured values.

It is preferable that the thickness of the first porous PTFE membrane 1be larger than the thickness of the second porous PTFE membrane 2,because in this case the effect on the resistance to clogging with oilmist is further enhanced. When the thickness of the first porous PTFEmembrane 1 is larger than the thickness of the second porous PTFEmembrane 2, the first porous PTFE membrane 1 collects relatively largeparticles of oil mist in advance on the upstream side in the air flowdirection while the second porous PTFE membrane 2 collects smallerparticles of oil mist on the downstream side in the air flow direction.Thus, since both the first porous PTFE membrane 1 and second porous PTFEmembrane 2 can collect oil mist, clogging of the air filter medium canbe further reduced.

The thickness of the first porous PTFE membrane 1 is, for example, 7 to36 μm and preferably 12 to 24 μm. The value of the thickness is anaverage of thickness values measured at any number of points (fivepoints, for example) using a dial thickness gauge.

It is preferable that the porosity of the first porous PTFE membrane 1be higher than the porosity of the second porous PTFE membrane 2,because in this case the effect on the resistance to clogging with oilmist is further enhanced. When the porosity of the first porous PTFEmembrane 1 is higher than the porosity of the second porous PTFEmembrane 2, the first porous PTFE membrane 1 collects relatively largeparticles of oil mist in advance on the upstream side in the air flowdirection while the second porous PTFE membrane 2 collects smallerparticles of oil mist on the downstream side in the air flow direction.Thus, since both the first porous PTFE membrane 1 and second porous PTFEmembrane 2 can collect oil mist, clogging of the air filter medium canbe further reduced.

The porosity of the first porous PTFE membrane 1 is, for example, 90 to99%. The porosity can be measured by the following method. First, themembrane to be measured is cut into a piece of given shape (the shape ofa 6-cm-diameter circle, for example), and its volume and weight aredetermined. The results are substituted into the following expression tocalculate the porosity.Porosity (%)=100×(V−(W/D))/V

-   -   V: Volume (cm³)    -   W: Weight (g)    -   D: Density of PTFE (g/cm³)

The pressure drop across the first porous PTFE membrane 1 is, forexample, 10 to 45 Pa and preferably 15 to 40 Pa. The pressure dropacross the first porous PTFE membrane 1, the pressure drop across thesecond porous PTFE membrane 2 described later, and the pressure dropacross the air filter medium can be measured by the following method.The first porous PTFE membrane 1, second porous PTFE membrane 2, or airfilter medium is set in a circular holder with an effective area of 100cm², and air is passed through the first porous PTFE membrane 1, secondporous PTFE membrane 2, or air filter medium set in the holder. Thelinear flow velocity of the air passing through the first porous PTFEmembrane 1, second porous PTFE membrane 2, or air filter medium isadjusted to 5.3 cm/sec with the aid of a flowmeter, and then thepressure drop is measured with a pressure meter (manometer). Thepressure drop is measured eight times for the first porous PTFE membrane1, second porous PTFE membrane 2, or air filter medium, and the averageof the eight values is calculated.

In the present embodiment, the PF value of the first porous PTFEmembrane 1 is, for example, in the range of 6 to 8. When the PF value ofthe first porous PTFE membrane 1 is within this range, large particlesof oil mist can be preferentially collected by the first porous PTFEmembrane 1.

Among the properties of the porous PTFE membranes and air filter medium,the pressure drop and collection efficiency are important. One of thesetwo properties tends to deteriorate when the other is improved, and thistendency makes it difficult to simultaneously achieve a good balancebetween the two properties. The PF value is used as a measure forevaluation of how well balanced the pressure drop and collectionefficiency are. The PF value is determined by the following equation(1). A higher PF value indicates higher performance of the porous PTFEmembranes and air filter medium. In the equation (1), PL representspressure drop.PF value=[−log(permeability (%)/100)/(PL (Pa)/9.8)]×100  (1)Permeability (%)=100−(downstream concentration of particles/upstreamconcentration of particles)(%)  (2)

In the equation (2), the second term on the right side is determined byvalues obtained by measurement at a permeation rate of 5.3 cm/sec usingpoly-α-olefin (PAO) with a particle diameter of 0.10 to 0.20 μm. The PFvalue of the first porous PTFE membrane 1 can be measured by peeling theair-permeable fiber layer 3 and second porous PTFE membrane 2 from thefirst porous PTFE membrane 1. The same applies to measurement of the PFvalue of the second porous PTFE membrane 2.

<Second Porous PTFE Membrane 2>

The second porous PTFE membrane 2 collects small particles of oil mistthat cannot be collected by the first porous PTFE membrane 1, and thusincreases the amount of oil mist collected by the air filter media 10,20, 30, 40, 50, and 60.

As is clear from Examples described below, the contact angle of thefirst porous PTFE membrane 1 is different from the contact angle of thesecond porous PTFE membrane 2 due to differences in productionconditions.

In the present embodiment, the contact angle of the second porous PTFEmembrane 2 with water is smaller than the contact angle of the firstporous PTFE membrane 1 with water. Specifically, the contact angle ofthe second porous PTFE membrane 2 with water is less than 154°. When thesecond porous PTFE membrane 2 satisfies this condition, smaller-diameterparticles of oil mist can be collected by the second porous PTFEmembrane 2 and thus the collection efficiency of the air filter mediumis improved. The lower limit of the contact angle of the second porousPTFE membrane 2 is not particularly limited, and is, for example, 138°.

The average pore diameter of the second porous PTFE membrane 2 is, forexample, 0.1 to 3 μm, preferably 0.2 to 3 μm, and more preferably 0.6 to1.5 μm.

The thickness of the second porous PTFE membrane 2 is, for example, 1 μmor more and less than 7 μm and preferably 1 to 5 μm. The ratio of thethickness of the first porous PTFE membrane 1 to the thickness of thesecond porous PTFE membrane 2 is desirably more than 1.

The porosity of the second porous PTFE membrane 2 is, for example, 50%or more and less than 90%.

The pressure drop across the second porous PTFE membrane 2 is, forexample, 50 to 300 Pa, preferably 60 to 140 Pa, and more preferably 80to 120 Pa.

The PF value of the second porous PTFE membrane 2 is, for example, inthe range of 20 to 40. When the PF value of the second porous PTFEmembrane 2 is within this range, fine dust and oil mist can be collectedby the second porous PTFE membrane 2 and thus an air filter mediumhaving a high collection efficiency can be obtained.

Exemplary methods for producing the first porous PTFE membrane 1 andsecond porous PTFE membrane 2 will be described hereinafter.

First, a liquid lubricant is added and mixed with an unsintered PTFEfine powder. The PTFE fine powder used is not particularly limited andcan be a commercially-available product. The liquid lubricant used isnot particularly limited, as long as the liquid lubricant can wet thesurface of the PTFE fine powder and can be removed later. Examples ofliquid lubricants that can be used include: hydrocarbon oils such asnaphtha, white oil, liquid paraffin, toluene, and xylene; alcohols;ketones; and esters. Two or more liquid lubricants may be used incombination.

The proportion of the liquid lubricant added to the PTFE fine powder ischosen as appropriate depending, for example, on the type of the PTFEfine powder, the type of the lubricant oil, and the conditions of sheetforming described later. For example, the amount of the liquid lubricantis 15 to 35 parts by weight with respect to 100 parts by weight of thePTFE fine powder.

Next, the mixture of the unsintered PTFE fine powder and the liquidlubricant is formed into a sheet shape without sintering, and thus asheet-shaped body of PTFE is obtained. Examples of the method for sheetforming include: a rolling method in which the mixture is extruded intoa rod shape and then the rod-shaped body is flattened with a pair ofrolls; and an extrusion method in which the mixture is extruded into aplate shape to obtain a sheet-shaped body. The sheet-shaped body made bysuch a method is in the form of a strip. Two or more methods may becombined to accomplish the sheet forming. The thickness of thesheet-shaped body of PTFE is chosen as appropriate depending, forexample, on the conditions of the subsequent stretching and is, forexample, 0.1 to 0.5 mm.

The liquid lubricant contained in the sheet-shaped body of PTFE ispreferably removed by a method such as heating or extraction before thestretching step subsequently performed. Examples of the solvent used forextraction include, but are not particularly limited to, normal-decane,dodecane, naphtha, kerosene, and liquid paraffin.

Next, the sheet-shaped body of PTFE is stretched. The stretching methodis preferably biaxial stretching. When the first porous PTFE membrane 1and the second porous PTFE membrane 2 are produced by stretchingsheet-shaped bodies of PTFE, the conditions such as the stretchingtemperature and stretching ratio need to be adjusted to achieve adesired contact angle for each membrane.

When the first porous PTFE membrane 1 is produced, the sheet-shaped bodyof PTFE is stretched while being heated at a temperature equal to orhigher than the melting point of PTFE. The sheet-shaped body of PTFE isstretched in the longitudinal direction (machine direction (MD)), forexample, at 370 to 380° C. The stretching ratio in the longitudinaldirection can be set so that the length after stretching is, forexample, 50 to 200 times, preferably 80 to 150 times, and morepreferably 90 to 100 times the length before stretching. Next, thesheet-shaped body of PTFE is stretched in the width direction(transverse direction (TD)), for example, at 130 to 400° C. Thestretching ratio in the width direction can be set so that the widthafter stretching is 5 to 8 times the width before stretching. Thestretching in the longitudinal direction at a temperature equal to orhigher than the melting point (327° C.) of PTFE tends to result in alarger contact angle than stretching at a temperature lower than themelting point of PTFE.

When the second porous PTFE membrane 2 is produced, the sheet-shapedbody of PTFE is stretched while being heated at a temperature lower thanthe melting point of PTFE. The sheet-shaped body of PTFE is stretched inthe longitudinal direction, for example, at 270 to 290° C. Thestretching ratio in the longitudinal direction can be set so that thelength after stretching is 15 to 40 times the length before stretching.Next, the sheet-shaped body of PTFE is stretched in the width direction,for example, at 120 to 130° C. The stretching ratio in the widthdirection can be set so that the width after stretching is 15 to 40times the width before stretching.

The first porous PTFE membrane 1 and the second porous PTFE membrane 2are produced by the above methods, and these membranes are bondedtogether directly or with the air-permeable fiber layer 3 interposedtherebetween. If necessary, the first air-permeable fiber layer 3 a isbonded to the first porous PTFE membrane 1, and the second air-permeablefiber layer 3 b is bonded to the second porous PTFE membrane 2. In thisway, the air filter media described with reference to FIGS. 1 to 6 areobtained.

PTFE is generally in a sintered state, unsintered state, or intermediatestate (hereinafter may be referred to as “half-sintered state”)depending on the condition of crystal transformation. When PTFE iscompletely sintered, one endothermic peak is observed around 325° C. indifferential scanning calorimetry (DSC). When PTFE is completelyunsintered, one endothermic peak is observed typically around 336° C. inDSC. Depending on thermal history, however, there may be two separatepeaks around 325° C. and 336° C. even when PTFE is in the unsinteredstate.

An apparent or potential endothermic peak observed in DSC typicallyaround 336° C. (330 to 340° C.) can confirm that PTFE particles remainpartially unsintered. In the completely sintered state, an endothermicpeak exists only around 325° C. and even a potential peak cannot beobserved around 336° C. As shown above, the sintering state of PTFE canbe easily examined by means of DSC.

<Air-Permeable Fiber Layer 3>

As shown in FIGS. 2 to 6, the air filter medium of the presentembodiment may include the air-permeable fiber layer 3. A materialhaving sufficient air permeability is used as the air-permeable fiberlayer 3. A material constituted by fibers such as short fibers andfilaments and having higher air permeability than the first porous PTFEmembrane 1 and second porous PTFE membrane 2 can be used as theair-permeable fiber layer 3, and examples of such a material includenon-woven fabrics, woven fabrics, meshes (reticulated sheets), and otherporous materials. Among these, non-woven fabrics are preferred becausethey are superior in terms of strength, flexibility, and workability.

The average fiber diameter of the fibers constituting the air-permeablefiber layer 3 is, for example, 10 to 30 μm and preferably 15 to 25 μm.

The mass per unit area of the air-permeable fiber layer 3 is, forexample, 15 to 300 g/m² and preferably 15 to 100 g/m² in view of the airpermeability of the air filter media 20, 30, 40, 50, and 60 and the easeof handling of the air filter media 20, 30, 40, 50, and 60 in pleating.The thickness of the air-permeable fiber layer 3 is preferably 130 to200 μm in view of the air permeability of the air filter media 20, 30,40, 50, and 60, the ease of handling of the air filter media 20, 30, 40,50, and 60 in pleating, and the overall thickness of the air filtermedia 20, 30, 40, 50, and 60.

The air filter media 40, 50, and 60 described with reference to FIGS. 4to 6 have the air-permeable fiber layer 3 (first air-permeable fiberlayer 3 a) disposed upstream of the first porous PTFE membrane 1. Whenthe mass per unit area of this air-permeable fiber layer 3 is large, oilmist is likely to be collected by the air-permeable fiber layer 3.Accordingly, the mass per unit area of the air-permeable fiber layer 3disposed upstream of the first porous PTFE membrane 1 is, for example,30 to 260 g/m² and preferably 30 to 200 g/m². In the air filter media 50and 60 described with reference to FIGS. 5 and 6, the mass per unit areaof the air-permeable fiber layers 3 (second air-permeable fiber layer 3b and third air-permeable fiber layer 3 c) disposed downstream of thefirst porous PTFE membrane 1 can be determined in view of reducing theincrease in pressure drop. The mass per unit area of the air-permeablefiber layers 3 disposed downstream of the first porous PTFE membrane 1is, for example, equal to or smaller than the mass per unit area of theair-permeable fiber layer 3 disposed upstream of the first porous PTFEmembrane 1. The mass per unit area of the air-permeable fiber layers 3disposed downstream of the first porous PTFE membrane 1 is, for example,15 to 100 g/m² and preferably 15 to 30 g/m². All of the air-permeablefiber layers 3 of the air filter medium 50 (or 60) may have the samestructure and properties.

Examples of the material of the fibers constituting the air-permeablefiber layer 3 include, but are not particularly limited to: polyolefinssuch as polyethylene (PE) and polypropylene (PP); polyesters such aspolyethylene terephthalate (PET); polyamides; and composites thereof.The fibers constituting the air-permeable fiber layer 3 preferablycontain a polyolefin with a low melting point, in particularpolyethylene, in view of easy and reliable bonding between the firstporous PTFE membrane 1 or second porous PTFE membrane 2 and theair-permeable fiber layer 3.

The air-permeable fiber layer 3 is preferably constituted by compositefibers having a core-sheath structure in which the core component has ahigher melting point than the sheath component. A material with arelatively high melting point, such as PET, is used as the corecomponent, and a material with a relatively low melting point, such aspolyethylene, is used as the sheath component. Specific examples of thefibers having a core-sheath structure include: fibers having a coreportion made of PET and a sheath portion made of PE (PET/PE fibers); andfibers having a core portion made of PP and a sheath portion made of PE(PP/PE fibers). The use of the air-permeable fiber layer 3 constitutedby fibers having a core-sheath structure reduces heat-induced change inthe structure and thickness of the air-permeable fiber layer 3 when theair-permeable fiber layer 3 is laminated to the first porous PTFEmembrane 1 or second porous PTFE membrane 2 by heating. Additionally,the first porous PTFE membrane 1 and second porous PTFE membrane 2 canbe prevented from being damaged due to shrinkage of the air-permeablefiber layer 3. In view of easy and reliable bonding between the firstporous PTFE membrane 1 or second porous PTFE membrane 2 and theair-permeable fiber layer 3, the air-permeable fiber layer 3 ispreferably constituted by PET/PE fibers.

Examples of the method for joining the first porous PTFE membrane 1,second porous PTFE membrane 2, and air-permeable fiber layer 3 togetherinclude heat-assisted nip lamination and lamination using an infraredheater (see JP 2003-190749 A). Of these, the lamination using aninfrared heater is preferred because this lamination can achieve strongbonding without decreasing the thickness of each layer. When theair-permeable fiber layer 3 is constituted by fibers having acore-sheath structure, it is preferable that the temperature of heatingof the air-permeable fiber layer 3 be set equal to or higher than thesoftening point (preferably equal to or higher than the melting point)of the sheath component and lower than the melting point of the corecomponent.

The order of stacking of the first porous PTFE membrane 1, second porousPTFE membrane 2, and air-permeable fiber layer 3 is not limited, as longas the first porous PTFE membrane and the second porous PTFE membraneare arranged so that an air flow moving from the first main surface 11to the second main surface 12 passes through the first porous PTFEmembrane and subsequently through the second porous PTFE membrane. Theremay be a portion where a plurality of the first porous PTFE membranes 1are contiguously stacked, there may be a portion where a plurality ofthe second porous PTFE membranes 2 are contiguously stacked, and theremay be a portion where a plurality of the air-permeable fiber layers 3are contiguously stacked. The air-permeable fiber layers 3 may be thesame or different from each other.

The pressure drop across the air filter medium is, for example, 60 to350 Pa, preferably 80 to 270 Pa, and more preferably 100 to 200 Pa.

The air filter medium of the present embodiment has excellent resistanceto clogging with oil mist. When poly-α-olefin (hereinafter referred toas “PAO”) in the form of polydisperse particles with an average particlediameter of 0.15 μm is passed through the air filter medium at aconcentration of 20 to 40 g/m³ and a linear flow velocity of 5.3 cm/secto measure the change in pressure drop, the amount of PAO collected bythe air filter medium is, for example, 20 mg/m²/Pa or more, preferably70 mg/m²/Pa or more, more preferably 90 mg/m²/Pa or more, andparticularly preferably 100 mg/m²/Pa or more, at a time point where thepressure drop reaches 500 Pa. The upper limit of the amount of collectedPAO is not particularly defined and is, for example, 200 mg/m²/Pa. Theamount of collected PAO (mg/m²/Pa) is determined by dividing an increasein weight of the air filter medium (the weight of PAO) (mg) by the area(m²) of the air filter medium and by further dividing the resultingvalue by an increase in pressure drop (500−(pressure drop at the startof measurement)) (Pa). For example, “Durasyn 164” manufactured by INEOScan be used as the PAO. The polydisperse PAO with an average particlediameter of 0.15 μm can be generated, for example, using aconstant-output aerosol atomizer (“TSI No. 3076” manufactured by TOKYODYLEC CORP.).

The air filter medium of the present embodiment further has excellentresistance to clogging with dust. When NaCl in the form of polydisperseparticles with an average particle diameter of 0.5 μm is passed throughthe air filter medium at a concentration of 1 to 3 g/m³ and a linearflow velocity of 5.3 cm/sec to measure the change in pressure drop, theamount of NaCl collected by the air filter medium is, for example, 8mg/m²/Pa or more, preferably 9 mg/m²/Pa or more, more preferably 12mg/m²/Pa or more, and particularly preferably 17 mg/m²/Pa or more, at atime point where the pressure drop reaches 500 Pa. The upper limit ofthe amount of collected NaCl is not particularly defined and is, forexample, 20 mg/m²/Pa. The amount of collected NaCl (mg/m²/Pa) isdetermined by dividing an increase in weight of the air filter medium(the weight of NaCl) (mg) by the area (m²) of the air filter medium andby further dividing the resulting value by an increase in pressure drop(500−(pressure drop at the start of measurement)) (Pa). The polydisperseNaCl with an average particle diameter of 0.5 μm can be generated, forexample, using a constant-output aerosol atomizer (“TSI No. 3076”manufactured by TOKYO DYLEC CORP.).

The collection efficiency of the air filter medium of the presentembodiment, as measured using bis(2-ethylhexyl) phthalate with anaverage particle diameter of 0.1 to 0.2 μm at a permeation rate of 5.3cm/sec, is, for example, 98 to 99.999995%, preferably 99.5 to 99.99999%,and more preferably 99.95 to 99.99995%. The air filter medium of thepresent embodiment may be an air filter medium complying with HEPA grade(high-efficiency particulate air grade) specified in Japanese IndustrialStandard (JIS) Z 8122 (2000) or may be an air filter medium complyingwith ULPA grade (ultra-low penetration air grade) specified in the samestandard.

The air filter medium of the present embodiment may be pleated by aknown technique. The pleating is accomplished, for example, by using areciprocating machine to fold the filter medium along mountain andvalley folds arranged alternately in parallel on the surface of thefilter medium and thereby form the medium into a series of W-shapes. Thepleated air filter medium may be called an air filter pack. The airfilter pack may be provided with a spacer to maintain the pleated shape.A string of resin, called a bead, is often used as the spacer. The beadis disposed on the filter medium to extend in a direction perpendicularto the mountain (valley) folds (in such a direction as to traverse themountains and valleys). Preferably, a plurality of such beads aredisposed on the filter medium to extend in this direction withpredetermined intervals therebetween. The beads are disposed, forexample, on both of the front and back sides of the filter medium. Thebeads are typically formed by melting a resin such as polyamide andpolyolefin and applying the molten resin.

If necessary, the pleated air filter medium (air filter pack 4) isprocessed into an air filter unit 70 shown in FIG. 7A by supporting theperipheral portion of the air filter pack 4 with a frame (supportframe). Depending, for example, on the intended use of the air filter, amember made of metal or resin may be used as a frame 5 surrounding theperiphery of the air filter pack. When a frame made of resin is used,the pleated air filter medium may be fixed to the frame simultaneouslywith formation of the frame by injection molding.

As shown in FIG. 7B, a pleat distance P (distance between peaks ofadjacent mountains) of the pleated air filter medium 4 is adjusted to awidth which allows the air filter medium 4 to have a sufficient surfacearea. The pleat distance P is adjusted to the range of, for example,2.54 to 12.7 mm and preferably 3.18 to 6.35 mm. For the same reason, apleat height h of the air filter medium 4 is adjusted to the range of,for example, 5 to 300 mm and preferably 20 to 250 mm. The value of(pleat distance P)/(pleat height h) is, for example, 0.25 or less andpreferably 0.22 or less.

The frame 5 may be made of a metallic material such as aluminum,stainless steel, a plated steel sheet, and coated steel sheet, or may bemade of a resin material such as polyolefin, polyamide (includingaromatic polyamide), polyurethane, polyester, polystyrene (such as ABS),and polycarbonate. The frame 5 may alternatively be made of a woodmaterial such as a fire-retardant plywood sheet and a plywood sheet.

As described with reference to FIGS. 1 to 6, the air filter medium ofthe present embodiment has front and back sides distinguished from eachother. If the second porous PTFE membrane 2 is disposed on the upstreamside in the air flow direction while the first porous PTFE membrane 1 isdisposed on the downstream side in the air flow direction, sufficienteffect on the resistance to clogging with oil mist cannot be achieved.The front and back sides can be mistakenly switched, for example, whenthe air filter medium is subjected to a process such as rewinding inslitting (the process of adjusting the dimensions of the air filtermedium by cutting) and pleating. To solve this problem, theconfigurations described hereinafter can be employed.

In the air filter media 50 and 60 described with reference to FIGS. 5and 6, the first air-permeable fiber layer 3 a and the secondair-permeable fiber layer 3 b may be each an embossed non-woven fabric;in this case, for example, the embossing pattern of the firstair-permeable fiber layer 3 a is different from the embossing pattern ofthe second air-permeable fiber layer 3 b. With such a configuration, thefirst main surface 11 and the second main surface 12 can bedistinguished to prevent the front and back sides from being mistakenlyswitched. The term “embossed non-woven fabric” refers to a non-wovenfabric subjected to embossing. Specifically, an embossed non-wovenfabric is a non-woven fabric having one or more recessed portions andone or more projecting portions. The embossed non-woven fabric hashigher stiffness and higher strength than an unembossed non-woven fabricas thick as the embossed non-woven fabric. The embossed non-woven fabrichas an indented pattern or, in other words, the embossed non-wovenfabric has a sea-island structure when viewed in plan.

Examples of embossed non-woven fabrics having different embossingpatterns include a T-type embossed non-woven fabric shown in FIG. 8A andan S-type embossed non-woven fabric shown in FIG. 8B. In the T-typeembossed non-woven fabric, as shown in FIG. 8A, elliptical portionscorresponding to “islands” (where the fibers are not melted) areprojecting portions, and a portion corresponding to the sea (where thefibers are melted) is a recessed portion. The T-type embossed non-wovenfabric typically has a single, continuous recessed portion and aplurality of projecting portions. The T-type embossed non-woven fabricmay have a plurality of recessed portions separate from each other. Inthe S-type embossed non-woven fabric, as shown in FIG. 8B, circularportions corresponding to “islands” (where the fibers are melted) arerecessed portions, and a portion corresponding to the “sea” (where thefibers are not melted) is a projecting portion. The S-type embossednon-woven fabric typically has a plurality of recessed portions and asingle, continuous projecting portion. The S-type embossed non-wovenfabric may have a plurality of projecting portions separate from eachother. With the use of these embossed non-woven fabrics, it is easier toachieve high air permeability and high bond strength.

Even if embossed non-woven fabrics of the same type are used, the firstmain surface 11 and the second main surface 12 can be distinguished whenthe embossed area ratio in the embossed non-woven fabric used as thefirst air-permeable fiber layer 3 a is sufficiently different from theembossed area ratio in the embossed non-woven fabric used as the secondair-permeable fiber layer 3 b. The term “embossed area ratio” as used todescribe an embossed non-woven fabric refers to the ratio of the area ofa recessed portion (portion where fibers are melted) or the total areaof a plurality of recessed portions to the area of the embossednon-woven fabric. The embossed area ratio can be calculated by thefollowing method. The surface of the non-woven fabric is observed with amicroscope such as an electron microscope at a given magnification (forexample, a magnification of 25 times). On the basis of the obtainedimage, the proportion of the embossed portion(s) (recessed portion(s))is calculated. In the case of an S-type non-woven fabric (see FIG. 8B),the recessed portions are assumed to be circular. In the case of aT-type non-woven fabric (see FIG. 8A), the projecting portions(unembossed portions) are assumed to be elliptical. The calculation ofthe embossed area ratio should be carried out using an image of anadequate size.

Embossed non-woven fabrics include a double-embossed non-woven fabrichaving two embossed surfaces and a single-embossed non-woven fabrichaving only one embossed surface. A double-embossed non-woven fabric maybe used as one of the first air-permeable fiber layer 3 a and the secondair-permeable fiber layer 3 b while a single-embossed non-woven fabricis used as the other. An embossed non-woven fabric may be used as one ofthe first air-permeable fiber layer 3 a and the second air-permeablefiber layer 3 b while an unembossed non-woven fabric is used as theother. These configurations also allow distinguishing between the firstmain surface 11 and the second main surface 12.

In another exemplary configuration, at least one selected from the firstmain surface 11 and the second main surface 12 is provided with anidentification mark that allows distinguishing between the first mainsurface 11 and the second main surface 12. This configuration isadvantageous because it is applicable to all of the air filter mediadescribed with reference to FIGS. 1 to 6.

The type of the identification mark that allows distinguishing betweenthe first main surface 11 and the second main surface 12 is notparticularly limited. The identification mark includes at least oneselected from the group consisting of a letter, a figure, and a symbol.Examples of the method for providing the identification mark include:applying an ink to at least one selected from the first main surface 11and the second main surface 12; and forming asperities on at least oneselected from the first main surface 11 and the second main surface 12.These methods make it possible to distinguish between the first mainsurface 11 and the second main surface 12. The asperities can be formed,for example, by pressing a portion of the air filter medium, by meltinga portion of the air filter medium, or by punching a portion of themember (for example, the first air-permeable fiber layer 3 a) formingthe first main surface 11 or second main surface 12. An embossingtechnique can be employed for the formation of asperities by pressing ormelting. The melting can be accomplished using a commercially-availablelaser marker.

In still another exemplary configuration, at least one selected from thefirst air-permeable fiber layer 3 a and the second air-permeable fiberlayer 3 b is colored, and the color of the first air-permeable fiberlayer 3 a is different from the color of the second air-permeable fiberlayer 3 b. For example, a colored non-woven fabric is used as one of thefirst air-permeable fiber layer 3 a and the second air-permeable fiberlayer 3 b. The colored non-woven fabric can be a non-woven fabriccontaining a colorant such as a pigment. The non-woven fabric may becolored with a chromatic color. In an example, one of the firstair-permeable fiber layer 3 a and the second air-permeable fiber layer 3b is constituted by a non-woven fabric colored with a chromatic colorwhile the other is constituted by an uncolored (white) non-woven fabric.Such a configuration also allows distinguishing between the first mainsurface 11 and the second main surface 12.

EXAMPLES

Hereinafter, the present invention will be described in detail withreference to Examples and Comparative Examples. The present invention isnot limited to Examples described below.

<Preparation of First Porous PTFE Membrane A>

A PTFE fine powder (“CD129E”, manufactured by Asahi Glass Co., Ltd.;standard specific gravity: 2.16) in an amount of 100 parts by weight wasuniformly mixed with 20 parts by weight of a liquid lubricant(dodecane), and the resulting mixture was preformed. Next, the preformwas formed into a rod shape by paste extrusion, and the rod-shaped bodywas passed between a pair of metal pressure rolls to obtain a long sheetwith a thickness of 200 μm. The long sheet was stretched in thelongitudinal direction at a stretching temperature (furnace temperature)of 375° C. in two stages; the sheet was stretched by a factor of 5 inthe first stage and by a factor of 20 in the second stage. The sheet wasthen stretched by a factor of 7 in the width direction at a stretchingtemperature (furnace temperature of a tenter) of 320° C. to prepare afirst porous PTFE membrane A. The pressure drop across the first porousPTFE membrane A was 15 Pa.

<Preparation of First Porous PTFE Membrane A1>

A PTFE fine powder (“CD129E”, manufactured by Asahi Glass Co., Ltd.) inan amount of 100 parts by weight was uniformly mixed with 20 parts byweight of a liquid lubricant (dodecane), and the resulting mixture waspreformed. Next, the preform was formed into a rod shape by pasteextrusion, and the rod-shaped body was passed between a pair of metalpressure rolls to obtain a long sheet with a thickness of 200 μm. Thelong sheet was stretched in the longitudinal direction at a stretchingtemperature of 375° C. in two stages; the sheet was stretched by afactor of 5 in the first stage and by a factor of 20 in the secondstage. The sheet was then stretched by a factor of 7 in the widthdirection at a stretching temperature of 300° C. to prepare a firstporous PTFE membrane A1. The pressure drop across the first porous PTFEmembrane A1 was 20 Pa.

<Preparation of First Porous PTFE Membrane A2>

A PTFE fine powder (“CD129E”, manufactured by Asahi Glass Co., Ltd.) inan amount of 100 parts by weight was uniformly mixed with 20 parts byweight of a liquid lubricant (dodecane), and the resulting mixture waspreformed. Next, the preform was formed into a rod shape by pasteextrusion, and the rod-shaped body was passed between a pair of metalpressure rolls to obtain a long sheet with a thickness of 200 μm. Thelong sheet was stretched in the longitudinal direction at a stretchingtemperature of 375° C. in two stages; the sheet was stretched by afactor of 4.5 in the first stage and by a factor of 20 in the secondstage. The sheet was then stretched by a factor of 6 in the widthdirection at a stretching temperature of 150° C. to prepare a firstporous PTFE membrane A2. The pressure drop across the first porous PTFEmembrane A2 was 40 Pa.

<Preparation of First Porous PTFE Membrane A3>

A PTFE fine powder (“CD129E”, manufactured by Asahi Glass Co., Ltd.) inan amount of 100 parts by weight was uniformly mixed with 20 parts byweight of a liquid lubricant (dodecane), and the resulting mixture waspreformed. Next, the preform was formed into a rod shape by pasteextrusion, and the rod-shaped body was passed between a pair of metalpressure rolls to obtain a long sheet with a thickness of 200 μm. Thelong sheet was stretched in the longitudinal direction in two stages;the sheet was stretched by a factor of 4 at a stretching temperature of150° C. in the first stage and by a factor of 2 at a stretchingtemperature of 375° C. in the second stage. The sheet was then stretchedby a factor of 8 in the width direction at a stretching temperature of200° C. to prepare a first porous PTFE membrane A3. The pressure dropacross the first porous PTFE membrane A3 was 2500 Pa.

<Preparation of First Porous PTFE Membrane B>

A PTFE fine powder (“Fluon (registered trademark) PTFE CD-123”,manufactured by Asahi Glass Co., Ltd.) in an amount of 100 parts byweight was uniformly mixed with 19 wt % of a liquid lubricant (naphtha),and the mixture was preformed under a condition of 20 kg/cm². Theresulting preform was then formed into a rod shape by paste extrusion,and the rod-shaped body was passed between a pair of metal pressurerolls to obtain a long sheet with a thickness of 200 μm. This sheet wasstretched by a factor of 14 in the longitudinal direction of the sheetat a stretching temperature of 290° C., and the sheet was then stretchedby a factor of 30 in the width direction of the sheet at a stretchingtemperature of 80° C. using a tenter method. An unsintered porous PTFEmembrane was thus obtained. This unsintered porous PTFE membrane washeat-treated at 400° C. for 10 seconds with its dimensions fixed. Asintered first porous PTFE membrane B was thus obtained. The pressuredrop across the first porous PTFE membrane B was 110 Pa.

<Preparation of First Porous PTFE Membrane C>

A PTFE fine powder (“Fluon (registered trademark) PTFE CD-123”,manufactured by Asahi Glass Co., Ltd.) in an amount of 100 parts byweight was uniformly mixed with 19 wt % of a liquid lubricant (naphtha),and the mixture was preformed under a condition of 20 kg/cm². Theresulting preform was then formed into a rod shape by paste extrusion,and the rod-shaped body was passed between a pair of metal pressurerolls to obtain a long sheet with a thickness of 200 μm. This sheet wasstretched by a factor of 15 in the longitudinal direction of the sheetat a stretching temperature of 290° C., and the sheet was then stretchedby a factor of 30 in the width direction of the sheet at a stretchingtemperature of 80° C. using a tenter method. An unsintered porous PTFEmembrane was thus obtained. This unsintered porous PTFE membrane washeat-treated at 400° C. for 10 seconds with its dimensions fixed. Asintered first porous PTFE membrane C was thus obtained. The pressuredrop across the first porous PTFE membrane C was 100 Pa.

<Preparation of Second Porous PTFE Membrane D>

A PTFE fine powder (“POLYFLON (registered trademark) PTFE F-104”,manufactured by Daikin Industries, Ltd.) in an amount of 100 parts byweight was uniformly mixed with 19 wt % of a liquid lubricant (naphtha),and the mixture was preformed under a condition of 20 kg/cm². Theresulting preform was then formed into a rod shape by paste extrusion,and the rod-shaped body was passed between a pair of metal pressurerolls to obtain a long sheet with a thickness of 200 μm. This sheet wasstretched by a factor of 35 in the longitudinal direction of the sheetat a stretching temperature of 280° C., and the sheet was then stretchedby a factor of 35 in the width direction of the sheet at a stretchingtemperature of 120° C. using a tenter method. An unsintered porous PTFEmembrane was thus obtained. This unsintered porous PTFE membrane washeat-treated at 400° C. for 10 seconds with its dimensions fixed. Asintered second porous PTFE membrane D was thus obtained. The pressuredrop across the second porous PTFE membrane D was 80 Pa.

<Preparation of Second Porous PTFE Membrane E>

A PTFE fine powder (“POLYFLON (registered trademark) PTFE F-104”,manufactured by Daikin Industries, Ltd.) in an amount of 100 parts byweight was uniformly mixed with 20 parts by weight of a liquid lubricant(dodecane), and the resulting mixture was preformed. Next, the preformwas formed into a rod shape by paste extrusion, and the rod-shaped bodywas passed between a pair of metal pressure rolls to obtain a long sheetwith a thickness of 200 μm. The long sheet was stretched by a factor of18 in the longitudinal direction at a stretching temperature of 280° C.and stretched by a factor of 35 in the width direction at a stretchingtemperature of 120° C. to prepare a second porous PTFE membrane E. Thepressure drop across the second porous PTFE membrane E was 140 Pa.

<Preparation of Second Porous PTFE Membrane F>

A PTFE fine powder (“POLYFLON (registered trademark) PTFE F-104”,manufactured by Daikin Industries, Ltd.) in an amount of 100 parts byweight was uniformly mixed with 20 parts by weight of a liquid lubricant(dodecane), and the resulting mixture was preformed. Next, the preformwas formed into a rod shape by paste extrusion, and the rod-shaped bodywas passed between a pair of metal pressure rolls to obtain a long sheetwith a thickness of 500 μm. The long sheet was stretched by a factor of23 in the longitudinal direction at a stretching temperature of 280° C.and stretched by a factor of 35 in the width direction at a stretchingtemperature of 120° C. to prepare a second porous PTFE membrane F. Thepressure drop across the second porous PTFE membrane F was 220 Pa.

<Preparation of Second Porous PTFE Membrane G>

The first porous PTFE membrane B was used as a second porous PTFEmembrane G.

<Preparation of Second Porous PTFE Membrane I>

A PTFE fine powder (“POLYFLON (registered trademark) PTFE F-104”,manufactured by Daikin Industries, Ltd.) in an amount of 100 parts byweight was uniformly mixed with 19 wt % of a liquid lubricant (naphtha).The resulting mixture was preformed under a condition of 20 kg/cm², andthe resulting preform was then formed into a rod shape by pasteextrusion. The rod-shaped body was passed between a pair of metalpressure rolls to obtain a long sheet with a thickness of 200 μm. Thissheet was stretched by a factor of 37 in the longitudinal direction ofthe sheet at a stretching temperature of 280° C., and the sheet was thenstretched by a factor of 35 in the width direction of the sheet at astretching temperature of 140° C. using a tenter method. An unsinteredporous PTFE membrane was thus obtained. This unsintered porous PTFEmembrane was heat-treated at 400° C. for 10 seconds with its dimensionsfixed. A sintered second porous PTFE membrane I was thus obtained. Thepressure drop across the second porous PTFE membrane I was 60 Pa.

<Air-Permeable Fiber Layer>

A non-woven fabric manufactured by UNITIKA LTD., “ELEVES S0303WDO”(core-sheath structure (core component: PET, sheath component: PE), massper unit area: 30 g/m², apparent density: 0.136 g/cm³, embossed arearatio: 15%, thickness: 0.22 mm), was used as an air-permeable fiberlayer.

Examples 1 to 4 and Comparative Examples 1 to 3

For the first porous PTFE membranes and the second porous PTFEmembranes, the contact angle was measured by the method previouslydescribed. A commercially-available contact angle meter (OCA 30,manufactured by DataPhysics Instruments GmbH) was used for the contactangle measurement. For the first porous PTFE membranes and the secondporous PTFE membranes, the pressure drop and collection efficiency weremeasured in advance by the following methods and the PF value wasdetermined by the equations (1) and (2) previously described. Theresults are shown in Table 1.

The first porous PTFE membranes, the second porous PTFE membranes, andthe above air-permeable fiber layer were combined as shown in Table 1.The first air-permeable fiber layer, the first porous PTFE membrane, thethird air-permeable fiber layer, the second porous PTFE membrane, andthe second air-permeable fiber layer were stacked in this order, andthey were thermally laminated by passing the stack between a pair ofrolls heated to 80° C. In this way, air filter media having a multilayerstructure as shown in FIG. 6 were produced.

For the air filter media thus obtained, the pressure drop, the amount ofcollected PAO, the amount of collected NaCl, and the collectionefficiency were measured by the following methods. The PF value of eachair filter medium was determined by the equations (1) and (2) previouslydescribed. The results are shown in Table 1.

<Pressure Drop>

Each air filter medium was set in a circular holder with an effectivearea of 100 cm². Air was passed through the air filter medium set in theholder, the linear flow velocity of the air passing through the airfilter medium was adjusted to 5.3 cm/sec with the aid of a flowmeter,and then the pressure drop was measured with a pressure meter(manometer). For each air filter medium, the pressure drop was measuredeight times, and the average of the eight values was calculated.

<Amount of Collected PAO>

Each air filter medium was set in the same device as in the pressuredrop measurement. PAO in the form of polydisperse particles with anaverage particle diameter of 0.15 μm (“Durasyn 164” manufactured byINEOS) was passed through the air filter medium at a concentration of 20to 40 g/m³ and a linear flow velocity of 5.3 cm/sec using aconstant-output aerosol atomizer (“TSI No. 3076” manufactured by TOKYODYLEC CORP.), and the change in pressure drop was measured with apressure meter (manometer). The weight (mg) of the air filter medium wasmeasured at a time point where the pressure drop reached 500 Pa. Anincrease in weight of the air filter medium relative to the weight ofthe air filter medium that had not been subjected to the pressure dropmeasurement was divided by the area (m²) of the air filter medium, andthe resulting value was further divided by an increase in pressure drop(500−(pressure drop at the start of measurement) (Pa). The value thusobtained was defined as the amount of collected PAO (mg/m²/Pa).

<Amount of Collected NaCl>

Each air filter medium was set in the same device as in the pressuredrop measurement. NaCl in the form of polydisperse particles with anaverage particle diameter of 0.5 μm was passed through the air filtermedium at a concentration of 1 to 3 g/m³ and a linear flow velocity of5.3 cm/sec using a constant-output aerosol atomizer (“TSI No. 3076”manufactured by TOKYO DYLEC CORP.), and the change in pressure drop wasmeasured with a pressure meter (manometer). The weight (mg) of the airfilter medium was measured at a time point where the pressure dropreached 500 Pa. An increase in weight of the air filter medium relativeto the weight of the air filter medium that had not been subjected tothe pressure drop measurement was divided by the area (m²) of the airfilter medium, and the resulting value was further divided by anincrease in pressure drop (500−(pressure drop at the start ofmeasurement) (Pa). The value thus obtained was defined as the amount ofcollected NaCl (mg/m²/Pa).

<Collection Efficiency>

Each air filter medium was set in the same device as in the pressuredrop measurement, and the linear flow velocity of gas passing throughthe air filter medium was adjusted to 5.3 cm/sec. Air containingpoly-α-olefin (PAO) particles with a particle diameter of 0.1 to 0.2 μmat a concentration of about 1×10⁹ particles/L was passed through the airfilter medium. The concentration of the PAO particles present downstreamof the air filter medium was measured with a particle counter, and thecollection efficiency (%) was determined by the following equation.Collection efficiency={1−(downstream concentration of PAOparticles/upstream concentration of PAO particles)}×100

TABLE 1 Comparative Comparative Comparative Example 1 Example 2 Example3 Example 4 Example 1 Example 2 Example 3 First Reference A A1 A2 A1 B CA3 porous sign PTFE Pressure 15 20 40 20 110 100 2500 membrane drop (Pa)Contact 155 155 157 155 152 152 138 angle (degrees) PF value 6.3 6.4 7.46.4 19.2 22.6 3.1 Second Reference D E F I G F D porous sign PTFEPressure 80 140 220 60 110 220 80 membrane drop (Pa) Contact 153 151 148153 152 148 153 angle (degrees) PF value 20.8 23.1 23.6 17.9 19.2 23.620.8 Pressure drop (Pa) 95 160 260 80 220 320 2580 Collection efficiency98 99.95 99.9995 98.371 99.995 99.9999974 99.999999 (%) PF value 17.520.2 20.0 21.9 19.2 23.3 3.0 Amount of collected 121.77 71.16 74.4 21.45.47 8.5 Unmeasurable PAO (mg/m²/Pa) Amount of collected 12.66 10.109.62 9.0 3.52 14.5 Unmeasurable NaCl (mg/m²/Pa)

The PF values of the first porous PTFE membranes A, A1, and A2 were low.The contact angles of the first porous PTFE membranes A, A1, and A2were, however, larger than the contact angles of the first porous PTFEmembranes A3, B, and C. In Examples 1 to 4, the contact angles of thesecond porous PTFE membranes were in the range of 148° to 153°.Specifically, the contact angles of the second porous PTFE membranes D,E, F, and I were 153°, 151°, 148°, and 153°, respectively. When the airfilter media of Examples 1 to 4 are compared with the air filter mediaof Comparative Examples 1 and 2, it is seen that the amount of collectedPAO was larger for the air filter media of Examples 1 to 4. That is, theair filter media of Examples 1 to 4 yielded a smaller increase inpressure drop with collection of oil mist and were less clogged with oilmist than the air filter media of Comparative Examples 1 and 2. Theamount of collected PAO and the amount of collected NaCl were unable tobe measured for the air filter medium of Comparative Example 3 becausethe pressure drop was too large.

INDUSTRIAL APPLICABILITY

The air filter medium of the present invention can be employed forvarious applications such as use as an intake air filter medium forturbines, use as a filter medium for outdoor air conditioners, use as anair filter medium for clean rooms intended for medical treatment orpharmaceutical operation, use as a filter medium for masks, and use as afilter medium for general home electric appliances. The air filtermedium of the present invention is particularly suitable for use as anair filter medium to be subjected to a process such as pleating.

The invention claimed is:
 1. An air filter medium has a first mainsurface and a second main surface, the air filter medium comprising: afirst porous PTFE membrane; a second porous PTFE membrane; and the firstporous PTFE membrane and the second porous PTFE membrane are arranged sothat an air flow moving from the first main surface to the second mainsurface passes through the first porous PTFE membrane and subsequentlythrough the second porous PTFE membrane, a contact angle of the firstporous PTFE membrane with water is in the range of 155° to 157°, and acontact angle of the second porous PTFE membrane with water is in therange of 148° to 153°.
 2. The air filter medium according to claim 1,wherein when poly-α-olefin in the form of polydisperse particles with anaverage particle diameter of 0.15 μm is passed through the air filtermedium at a concentration of 20 to 40 g/m³ and a linear flow velocity of5.3 cm/sec to measure change in pressure drop, an amount ofpoly-a-olefin collected by the air filter medium is 20 mg/m²/Pa or moreat a time point where the pressure drop reaches 500 Pa.
 3. The airfilter medium according to claim 1, wherein when NaCl in the form ofpolydisperse particles with an average particle diameter of 0.5 μm ispassed through the air filter medium at a concentration of 1 to 3 g/m³and a linear flow velocity of 5.3 cm/sec to measure change in pressuredrop, an amount of NaCl collected by the air filter medium is 8 mg/m²/Paor more at a time point where the pressure drop reaches 500 Pa.
 4. Theair filter medium according to claim 1, wherein the pressure drop acrossthe first porous PTFE membrane is 10 to 45 Pa.
 5. An air filter packcomprising the air filter medium according to claim 1, the air filtermedium being pleated.
 6. An air filter unit comprising the air filterpack according to claim 5 and a frame supporting the air filter pack.